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RESEARCH PRODUCT

Triple-Quantum Two-Dimensional 27Al Magic Angle Nuclear Magnetic Resonance Study of the Aluminum Incorporation in Calcium Silicate Hydrates

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Triple-quantum two-dimensional 27Al magic angle spinning nuclear magnetic resonance (27Al 3Q-MAS NMR) was used to characterize the substitution of Si4+ by Al3+ into the Te−Oc−Te structure of calcium silicate hydrates (C−S−H). This substitution was studied with C−S−H having an Oc/Te ratio of 1 and in equilibrium with Al(OH)3 in aqueous suspensions. In the absence of NaOH, no substitution into the C−S−H structure occurred. Addition of NaOH in the preparation increased the concentration of Al(OH)4- and favored substitution. The deficit of charge resulting from this substitution was compensated by the accommodation of sodium in the interlayer space of the C−S−H. Increasing levels of substituted silicon correspond to higher alkaline and lower calcium contents in the interlayer space. Two substitution sites were distinguished, corresponding to the bridging and nonbridging positions in the chains of tetrahedra. A high Altetra/(Si+Altetra) ratio indicated a redistribution of the aluminum tetrahedral sites to stab...