Poly[bis(μ-pentafluorobenzenethiolato)lead(II)]

6533b81ffe1ef96bd1278edc

RESEARCH PRODUCT

Poly[bis(μ-pentafluorobenzenethiolato)lead(II)]

Dieter Schollmeyer Cathrin Heller Holger Fleischer

subject

Crystallography Valence (chemistry)Chemistry Stereochemistry Atom General Materials Science General Chemistry Condensed Matter Physics Lone pair Layered structure

description

The title compound, [Pb(SC6F5)2]n, exhibits a layered structure containing two differently hexacoordinated PbII atoms. One is situated on a centre of inversion and is coordinated by six S atoms, its valence lone pair of electrons being consequently stereochemically inactive. The other Pb atom is pyramidally coordinated by three S atoms and forms three contacts to adjacent F atoms, the stereochemically active lone pair pointing towards the F3 plane.

year	journal	country	edition	language
2006-05-24	Acta Crystallographica Section E Structure Reports Online

https://doi.org/10.1107/s1600536806018563

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