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RESEARCH PRODUCT
Structure and fluxional behaviour of heptaleneirontricarbonyl and heptalenebis (Irontricarbonyl)
Klaus MüllenEmanuel VogelJohann LexNeil T. AllisonHans Schmicklersubject
chemistry.chemical_classificationBicyclic moleculeStereochemistryOrganic ChemistryCrystal structureNuclear magnetic resonance spectroscopyBiochemistrychemistry.chemical_compoundchemistryComputational chemistryDrug DiscoveryX-ray crystallographyHeptaleneChemical solutionMoleculeInorganic compounddescription
Abstract The synthesis of heptaleneirontricarbonyl ( 4 ) is described. The structures of 4 and of the closely related heptalenebis(irontricarbonyl) ( 3 ) are elucidated by NMR spectroscopy ( 1H and 13C) and by X-ray crystallography. Compounds 3 and 4 are shown by dynamic NMR to undergo an isodynamic 1 ,2-migration of the Fe(CO3)-groups as well as a carbonyl scrambling. The relevant kinetic data allow for a mechanistic discussion of the dynamics and a comparison with other irontricarbonyl complexes.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1987-01-01 | Tetrahedron |