Selective Preparation of Diamondoid Phosphonates

6533b81ffe1ef96bd1278f92

RESEARCH PRODUCT

Selective Preparation of Diamondoid Phosphonates

Michael Serafin Robert M. K. Carlson Peter R. Schreiner Natalie A. Fokina Jeremy E. P. Dahl Maria A. Gunawan Jean-cyrille Hierso Raisa I. Yurchenko Hélène Cattey Andrey A. Fokin Boryslav A. Tkachenko Didier Poinsot

subject

Phosphonic acid derivatives chemistry.chemical_compound chemistry Organic Chemistry Trifluoroacetic acid Organic chemistry Sequence (biology)Diamondoid Diamantane

description

We present an effective sequence for the preparation of phosphonic acid derivatives of the diamondoids diamantane, triamantane, [121]tetramantane, and [1(2,3)4]pentamantane. The reactions of the corresponding diamondoid hydroxy derivatives with PCl3 in sulfuric or trifluoroacetic acid give mono- as well as didichlorophosphorylated diamondoids in high preparative yields.

year	journal	country	edition	language
2014-05-21	The Journal of Organic Chemistry

https://doi.org/10.1021/jo500793m

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