High-nuclearity magnetic clusters: Magnetic interactions in clusters encapsulated by molecular metal oxides

6533b820fe1ef96bd1279913

RESEARCH PRODUCT

High-nuclearity magnetic clusters: Magnetic interactions in clusters encapsulated by molecular metal oxides

Eugenio Coronado Carlos J. Gómez-garcía José Ramón Galán-mascarós Juan J. Borrás-almenar

subject

Materials science Crystal chemistry Metal ions in aqueous solution Crystal structure Condensed Matter Physics Electronic Optical and Magnetic Materials Ion Metal Crystallography Ferromagnetism visual_art visual_art.visual_art_medium Antiferromagnetism Condensed Matter::Strongly Correlated Electrons Spin (physics)

description

Abstract The ability of the molecular metal oxides derived from the Keggin anion [PW 12 O 40 ] 3− to accommodate magnetic ions at specific sites, giving rise to polymetallic clusters with increasing spin nuclearities is discussed. Examples of magnetic clusters with three, four and nine metal ions exhibiting ferromagnetic exchange couplings or a coexistence of ferro- and antiferromagnetic couplings are reported.

year	journal	country	edition	language
1995-02-01	Journal of Magnetism and Magnetic Materials

https://doi.org/10.1016/0304-8853(94)01194-x

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