6533b820fe1ef96bd1279920

RESEARCH PRODUCT

trans-Bis(1H-benzimidazole-1-thione-κS)tetrachlorotellurium methanol disolvate

Holger FleischerDieter Schollmeyer

subject

biologychemistry.chemical_elementGeneral ChemistryCondensed Matter Physicsbiology.organism_classificationMedicinal chemistryCrystalSolventchemistry.chemical_compoundchemistryOctahedronAtomTetraImidazoleGeneral Materials ScienceMethanolTellurium

description

The Te atom in the title complex, trans-[TeCl4(C6H4N2H2CS)2]·2CH4O or C16H20Cl4N4O2S2Te, occupies a special position at a crystallographic inversion centre and has an octahedral coordination formed by four chloro ligands and the S atoms of two benz­imidazole–thione mol­ecules. The hydrogen-bond system involving the disordered solvent methanol mol­ecules links the tellurium complexes into the infinite two-dimensional aggregates in the crystal.

https://doi.org/10.1107/s1600536802012424