6533b820fe1ef96bd127993e

RESEARCH PRODUCT

[Ni(cyclam)(μ1,3-dca)2Cu(μ1,5-dca)2]:  A Genuine 3D Bimetallic Coordination Polymer Containing Both μ1,3- and μ1,5-Bidentate Dicyanamide Bridges and a Ferromagnetic Interaction between Copper(II) and Nickel(II) Ions

José Suárez-varelaFrancesc LloretIkram Ben MaimounEnrique Colacio

subject

DenticityCoordination polymerInorganic chemistrychemistry.chemical_elementCopperInorganic Chemistrychemistry.chemical_compoundNickelCrystallographychemistryFerromagnetismCyclamPhysical and Theoretical ChemistryBimetallic stripDicyanamide

description

The structure of [Ni(cyclam)(μ 1 , 3 -dca) 2 Cu(μ 1 , 5 -dca) 2 ], a genuine 3D dicyanamide-bridged bimetallic coordination polymer, is made up of 2D [Cu(μ- 1 , 5 dca) 2 ] n layers connected by [Ni(cyclam)(μ 1 , 3 -dca) 2 ] bridging moieties; it exhibits a ferromagnetic exchange interaction between copper(ll) and nickel(ll) ions through the μ 1 , 3 -bidentate dicyanamide bridges.

yearjournalcountryeditionlanguage
2005-04-30Inorganic Chemistry
https://doi.org/10.1021/ic050369v