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RESEARCH PRODUCT
Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers
José Antonio RealTomomi KoshiyamaAkio MishimaMasaaki Ohbasubject
Materials scienceSpin states010405 organic chemistryCoordination polymerInorganic chemistryPorous Coordination PolymersSpin transitionGeneral Chemistry010402 general chemistry01 natural sciencesMicelle0104 chemical scienceschemistry.chemical_compoundResponsivitychemistryChemical engineeringMaterials ChemistryMesocrystalPorositydescription
Mesocrystals of a porous coordination polymer {Fe(pz)[Pt(CN)4]} (1) showing spin transition were prepared by the reverse micelle method, and the size-controlled mesocrystal 1 kept its porous property and magnetic bistability and exhibited higher guest-responsivity with switching the spin state in both solid and aqueous suspension states than the bulk 1.
year | journal | country | edition | language |
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2017-01-01 | Journal of Materials Chemistry C |