6533b820fe1ef96bd12799d3

RESEARCH PRODUCT

Enhancement of guest-responsivity by mesocrystallization of porous coordination polymers

José Antonio RealTomomi KoshiyamaAkio MishimaMasaaki Ohba

subject

Materials scienceSpin states010405 organic chemistryCoordination polymerInorganic chemistryPorous Coordination PolymersSpin transitionGeneral Chemistry010402 general chemistry01 natural sciencesMicelle0104 chemical scienceschemistry.chemical_compoundResponsivitychemistryChemical engineeringMaterials ChemistryMesocrystalPorosity

description

Mesocrystals of a porous coordination polymer {Fe(pz)[Pt(CN)4]} (1) showing spin transition were prepared by the reverse micelle method, and the size-controlled mesocrystal 1 kept its porous property and magnetic bistability and exhibited higher guest-responsivity with switching the spin state in both solid and aqueous suspension states than the bulk 1.

https://doi.org/10.1039/c7tc00751e