6533b820fe1ef96bd1279b48

RESEARCH PRODUCT

Gas—liquid chromatographic analyses

Ilpo O.o. KorhonenKeijo Mäntykoski

subject

Polarity (international relations)ChromatographyCapillary actionChemistryOrganic ChemistryAnalytical chemistryGeneral MedicineMass spectrometryBiochemistryAnalytical ChemistryCapillary columnPolychlorinated Dibenzo-p-dioxinspolycyclic compoundsKovats retention indexheterocyclic compoundsGas chromatographySelectivityDispersion (chemistry)Retention timePolychlorinated dibenzofuransGas liquid chromatographic

description

Abstract The retention (I), dispersion (IM) and selectivity (I*) indices of sixteen polychlorinated dibenzo-p-dioxins and fourteen polychlorinated dibenzofurans were determined on a low-polarity HP-5 capillary column using a gas chromatograph connected with an ion-selective detector. IM and I* values were also calculated for all 73 dibenzo-p-dioxins from the di- to the octachloro isomer and for all possible 135 chlorinated dibenzofurans based on the predicted retention index data reported earlier. The effect of the position of chlorination is shown and the results are compared with those for several series of chlorinated aromatics.

yearjournalcountryeditionlanguage
1989-01-01Journal of Chromatography A
https://doi.org/10.1016/s0021-9673(01)89641-2