6533b820fe1ef96bd127a3cb

RESEARCH PRODUCT

Tris(cyclo-hexyl-ammonium) cis-di-chlorido-bis-(oxalato-κ(2) O (1),O (2))stann-ate(IV) chloride monohydrate.

Waly DialloModou SarrLaurent PlasseraudAminata Diasse-sarrHélène Cattey

subject

TrisMetal-Organic PapersDenticityStannateGeneral ChemistryCrystal structureCondensed Matter PhysicsBioinformaticsMedicinal chemistryChlorideOxalateIonchemistry.chemical_compoundchemistrymedicineGeneral Materials ScienceAmmoniummedicine.drug

description

The crystal structure of the title compound, (C6H14N)3[Sn(C2O4)2Cl2]Cl·H2O, contains three cyclohexylammonium cations, one stannate(IV) dianion, one isolated chloride anion and one lattice water molecule. The cyclohexylammonium cations adopt chair conformations. In the complex anion, two bidentate oxalate ligands and two chloride anions incispositions coordinate octahedrally to the central SnIVatom. The cohesion of the molecular entities is ensured by the formation of N—H...O, O—H...O, O—H...Cl and N—H...Cl interactions involving cations, anions and the lattice water molecule, giving rise to a layer-like arrangement parallel to (010).

10.1107/s1600536813026901https://pubmed.ncbi.nlm.nih.gov/24454022