Gitteröffnung durch reduktive kovalente Volumen‐Funktionalisierung von schwarzem Phosphor

6533b821fe1ef96bd127ae49

RESEARCH PRODUCT

Gitteröffnung durch reduktive kovalente Volumen‐Funktionalisierung von schwarzem Phosphor

Herwig Peterlik Christian Papp Haiko Wittkämper Andreas Görling Stefan Wild Mathias Grabau Miguel ÁNgel Rivero-crespo Antonio Leyva-pérez Frank Hauke Aleksandra Mitrovic Hans-peter Steinrück Katharina Werbach Michael Fickert Christian Neiss Gonzalo Abellán Gonzalo Abellán Thomas Pichler Vicent Lloret Andreas Hirsch Jose A. Vidal-moya

subject

Materials science 010405 organic chemistry General Medicine 010402 general chemistry 01 natural sciences 0104 chemical sciences

description

Eine chemisch-reduktive Volumen-Funktionalisierung von dünnlagigem schwarzem Phosphor (BP) gelang unter Verwendung von BP-Interkalationsverbindungen. Durch eine effektive reduktive Aktivierung wurde die kovalente Funktionalisierung des geladenen BP mit Alkylhalogeniden erzielt, wobei eine Öffnung des BP-Gitters und ein höherer Funktionalisierungsgrad als bei neutralen Reaktionsrouten resultieren.

year	journal	country	edition	language
2019-03-21	Angewandte Chemie

https://doi.org/10.1002/ange.201811181

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