Author: Mathias Grabau

0000000000481540

AUTHOR

Mathias Grabau

showing 2 related works from this author

Gitteröffnung durch reduktive kovalente Volumen‐Funktionalisierung von schwarzem Phosphor

2019

Eine chemisch-reduktive Volumen-Funktionalisierung von dünnlagigem schwarzem Phosphor (BP) gelang unter Verwendung von BP-Interkalationsverbindungen. Durch eine effektive reduktive Aktivierung wurde die kovalente Funktionalisierung des geladenen BP mit Alkylhalogeniden erzielt, wobei eine Öffnung des BP-Gitters und ein höherer Funktionalisierungsgrad als bei neutralen Reaktionsrouten resultieren.

Materials science010405 organic chemistryGeneral Medicine010402 general chemistry01 natural sciences0104 chemical sciencesAngewandte Chemie

researchProduct

Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus

2019

The chemical bulk reductive covalent functionalization of thin-layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes.

Materials scienceIntercalation (chemistry)reductive routeFOS: Physical sciencesHalideApplied Physics (physics.app-ph)010402 general chemistryblack phosphorus01 natural sciences7. Clean energyCatalysisBlack phosphorusCovalent functionalizationsymbols.namesakeLattice (order)MaterialsAlkylchemistry.chemical_classification010405 organic chemistryCommunicationQuímicaPhysics - Applied PhysicsGeneral ChemistryCommunicationsEspectroscòpia Raman0104 chemical sciencesCrystallographycovalent functionalizationchemistryBlack Phosphorusddc:540Raman spectroscopysymbolsSurface modification31P NMR spectroscopyRaman spectroscopy

researchProduct

PEPhysical Sciences and Engineering
- PE2Fundamental Constituents of Matter
  - PE2_1Theory of fundamental interactions
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  - PE2_3Experimental particle physics with accelerators
  - PE2_4Experimental particle physics without accelerators
  - PE2_6Nuclear, hadron and heavy ion physics
  - PE2_8Gas and plasma physics
  - PE2_5Classical and quantum physics of gravitational interactions
  - PE2_7Nuclear and particle astrophysics
  - PE2_9 Electromagnetism
  - PE2_10Atomic, molecular physics
  - PE2_11Ultra-cold atoms and molecules
  - PE2_18Equilibrium and non-equilibrium statistical mechanics: steady states and dynamics
  - PE2_14Lasers, ultra-short lasers and laser physics
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  - PE2_16Non-linear physics
  - PE2_12Optics, non-linear optics and nano-optics
  - PE2_13Quantum optics and quantum information
  - PE2_15Thermodynamics
- PE1Mathematics
  - PE1_1Logic and foundations
  - PE1_6Geometry and global analysis
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  - PE1_9Operator algebras and functional analysis
  - PE1_10ODE and dynamical systems
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  - PE1_11Theoretical aspects of partial differential equations
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  - PE1_15Generic statistical methodology and modelling
  - PE1_4 Algebraic and complex geometry
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  - PE1_5Lie groups, Lie algebras
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  - PE10_13Physical geography, geomorphology
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- PE11Materials Engineering
  - PE11_2Engineering of metals and alloys
  - PE11_1Engineering of biomaterials, biomimetic, bioinspired and bio-enabled materials
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  - PE11_8Engineering of alternative established or emergent materials
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  - PE11_11Porous materials engineering, e.g. covalent-organic, metal-organic, porous aromatic frameworks
  - PE11_12Semi-conducting and magnetic materials engineering
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  - PE11_14Computational methods for materials engineering
LSLife Sciences
- LS1Molecules of Life: Biological Mechanisms, Structures and Functions
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- LS2Integrative Biology: from Genes and Genomes to Systems
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  - LS4_1Organ and tissue physiology and pathophysiology
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  - LS4_3Physiology of ageing
  - LS4_2Comparative physiology
  - LS4_5Non-hormonal mechanisms of inter-organ and tissue communication
  - LS4_6Microbiome and host physiology
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  - LS4_11Haematopoiesis and blood diseases
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- LS3Cell Biology, Development, Stem Cells and Regeneration
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  - LS3_7Mechanobiology of cells, tissues and organs
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  - LS3_17Theoretical modelling in cellular, developmental and regenerative biology
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  - LS3_1Cell cycle, cell division and growth
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- LS5Neuroscience and Disorders of the Nervous System
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SHSocial Sciences and Humanities
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