6533b835fe1ef96bd129ed43

RESEARCH PRODUCT

Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus

Michael FickertChristian NeissJose A. Vidal-moyaHaiko WittkämperAntonio Leyva-pérezHans-peter SteinrückChristian PappKatharina WerbachAndreas GörlingGonzalo AbellánGonzalo AbellánHerwig PeterlikMiguel ÁNgel Rivero-crespoAndreas HirschStefan WildThomas PichlerVicent LloretAleksandra MitrovićFrank HaukeMathias Grabau

subject

Materials scienceIntercalation (chemistry)reductive routeFOS: Physical sciencesHalideApplied Physics (physics.app-ph)010402 general chemistryblack phosphorus01 natural sciences7. Clean energyCatalysisBlack phosphorusCovalent functionalizationsymbols.namesakeLattice (order)MaterialsAlkylchemistry.chemical_classification010405 organic chemistryCommunicationQuímicaPhysics - Applied PhysicsGeneral ChemistryCommunicationsEspectroscòpia Raman0104 chemical sciencesCrystallographycovalent functionalizationchemistryBlack Phosphorusddc:540Raman spectroscopysymbolsSurface modification31P NMR spectroscopyRaman spectroscopy

description

The chemical bulk reductive covalent functionalization of thin-layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes.

yearjournalcountryeditionlanguage
2019-03-21
10.1002/anie.201811181http://hdl.handle.net/10261/208520