6533b821fe1ef96bd127af56

RESEARCH PRODUCT

Manganese(iv) oxamato-catalyzed oxidation of secondary alcohols to ketones by dioxygen and pivalaldehyde

Rafael RuizAlly AukaulooYves JournauxRafael RuizAlly AukaulooIsabel FernándezJosé R. PedroAntonio L. RosellóBeatriz CerveraIsabel CastroM. Carmen Muñoz

subject

ManganesePivalic acidDioxygenUNESCO::QUÍMICA::Química inorgánicaUNESCO::QUÍMICAMetals and Alloyschemistry.chemical_elementGeneral ChemistryManganeseKetones:QUÍMICA::Química inorgánica [UNESCO]:QUÍMICA [UNESCO]CatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCatalysischemistry.chemical_compoundchemistryAlcoholsOxidationMaterials ChemistryCeramics and CompositesOxidation of secondary alcohols to ketonesOrganic chemistryManganese ; Oxidation ; Alcohols ; Ketones ; Dioxygen

description

A new manganese(IV) oxamato complex possessing a bis(moxo) dimanganese core has been synthesized, magnetically and structurally characterized, and found to catalyze the aerobic oxidation of secondary alcohols to ketones with cooxidation of pivalaldehyde to pivalic acid with good yields and high selectivities. Ruiz Garcia, Rafael, Rafael.Ruiz@uv.es ; Fernandez Picot, Isabel, Isabel.Fernandez@uv.es ; Pedro Llinares, Jose Ramon, Jose.R.Pedro@uv.es ; Rosello Arce, Antonio Luis, Antonio.L.Rosello@uv.es ; Castro Bleda, Isabel, Isabel.Castro@uv.es

yearjournalcountryeditionlanguage
1998-01-01
http://hdl.handle.net/10550/16764