6533b821fe1ef96bd127af8b

RESEARCH PRODUCT

The acid–base flow battery : Sustainable energy storage via reversible water dissociation with bipolar membranes

Ragne PärnamäeLuigi GurreriJan PostWillem Johannes Van EgmondAndrea CulcasiMichel SaakesJiajun CenEmil GoosenAlessandro TamburiniDavid A. VermaasMichele Tedesco

subject

Settore ING-IND/26 - Teoria Dello Sviluppo Dei Processi ChimiciEnergy storageFiltration and Separation02 engineering and technology010402 general chemistrylcsh:Chemical technology01 natural sciences7. Clean energyEnergy storagePeak demandReverse electrodialysisBipolar membraneChemical Engineering (miscellaneous)lcsh:TP1-1185lcsh:Chemical engineeringProcess engineeringbusiness.industryProcess Chemistry and Technologylcsh:TP155-156021001 nanoscience & nanotechnologyFlow batterybipolar membrane electrodialysi0104 chemical sciencesRenewable energyChemical energyElectricity generationPilot plant13. Climate actionFlow batteryPerspectiveBipolar membrane electrodialysisEnvironmental scienceElectricityWater dissociation0210 nano-technologybusinessreverse electrodialysi

description

The increasing share of renewables in electric grids nowadays causes a growing daily and seasonal mismatch between electricity generation and demand. In this regard, novel energy storage systems need to be developed, to allow large-scale storage of the excess electricity during low-demand time, and its distribution during peak demand time. Acid–base flow battery (ABFB) is a novel and environmentally friendly technology based on the reversible water dissociation by bipolar membranes, and it stores electricity in the form of chemical energy in acid and base solutions. The technology has already been demonstrated at the laboratory scale, and the experimental testing of the first 1 kW pilot plant is currently ongoing. This work aims to describe the current development and the perspectives of the ABFB technology. In particular, we discuss the main technical challenges related to the development of battery components (membranes, electrolyte solutions, and stack design), as well as simulated scenarios, to demonstrate the technology at the kW–MW scale. Finally, we present an economic analysis for a first 100 kW commercial unit and suggest future directions for further technology scale-up and commercial deployment.

10.3390/membranes10120409https://doi.org/10.3390/membranes10120409