6533b821fe1ef96bd127b651
RESEARCH PRODUCT
Hydrogenolysis of carbon–carbon σ-bonds using water catalysed by semi-rigid diiridium(iii) porphyrins
Ching Wai FongKin Shing ChanHo Yin YuClaude P. Grossubject
HydrogenChemistryReinforced carbon–carbonchemistry.chemical_elementEther02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnologyCleavage (embryo)01 natural sciencesPorphyrinCatalysis0104 chemical sciencesCatalysischemistry.chemical_compoundHydrogenolysisPolymer chemistryMaterials Chemistry0210 nano-technologydescription
Semi-rigid diiridium(III) porphyrin alkyls with m-xylyl and p-xylyl diether linkers were synthesized. They were found to be catalysts for the carbon–carbon σ-bond hydrogenolysis of [2.2]paracyclophane under neutral conditions using water as the hydrogen source. The ether linkages in semi-rigid diiridium(III) porphyrins are unstable and undergo cleavage during the reaction.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2019-01-01 | New Journal of Chemistry |