6533b821fe1ef96bd127b811
RESEARCH PRODUCT
Crystal structure of μ-oxido-1,1′κ2 O:O-bis{tetra-μ-oxido-1:2κ2 O:O;1:3κ2 O:O;2:3κ4 O:O-tris[1,2,3(η5)-pentamethylcyclopentadienyl]-trianglo-trititanium(IV)}
Avelino MartínAdrián Pérez-redondoCorrado Rizzolisubject
Triscrystal structureorganometallicOxidechemistry.chemical_elementNanotechnologytitanium oxideCrystal structureMedicinal chemistryMetalchemistry.chemical_compoundGeneral Materials Sciencepentamethylcyclopentadienyl ligandCrystallographybiologyGeneral ChemistryQuímicaCondensed Matter Physicsbiology.organism_classificationData ReportsTitanium oxideChemistrychemistryQD901-999visual_artvisual_art.visual_art_mediumTetrapentamethylcyclopentadienyl ligandTitaniumdescription
The title polynuclear organometallic titanium(IV) oxide, [{Ti3(η5-C5Me5)3(μ-O)4}2(μ-O)], exhibits two Ti3O4 cores bridged by an O atom located on a twofold axis. All metal centers present the typical three-legged piano-stool coordination environment, where one site is occupied by a pentamethylcyclopentadienyl ligand linked in an η5-coordination fashion, while three bridging O atoms fill the other three sites.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2015-04-01 | Acta Crystallographica Section E: Crystallographic Communications |