6533b821fe1ef96bd127c11c

RESEARCH PRODUCT

Miscibility of cyanine dyes in two-dimensional aggregates

V. BliznyukHelmuth Möhwald

subject

Absorption spectroscopyChemistryMetals and AlloysAnalytical chemistrySurfaces and InterfacesMiscibilityFluorescenceSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundElectron diffractionMonolayerMaterials ChemistryPhysical chemistryMoleculeCyanineSpectroscopy

description

Mixed aggregates of cyanine dyes at a charged lipid monolayer surface are studied by absorption spectroscopy, fluorescence microscopy and electron diffraction. We show that slight variations of the molecular structure can convert a system from being fully miscible to being immiscible, and also that the concentrations of dyes in the solution and in the crystal may deviate considerably. The different concentration in the solution and crystal was observed for a molecule where force field calculations indicated the existence of two isomers in solution and where probably only one fits into the lattice.

https://doi.org/10.1016/s0040-6090(94)06499-7