Giant Crown-Shaped Polytungstate Formed by Self-Assembly of CeIII-Stabilized Dilacunary Keggin Fragments

6533b821fe1ef96bd127c226

RESEARCH PRODUCT

Giant Crown-Shaped Polytungstate Formed by Self-Assembly of CeIII-Stabilized Dilacunary Keggin Fragments

Mónica Giménez-marqués José Ramón Galán-mascarós Pablo Vitoria Santiago Reinoso Juan M. Gutiérrez-zorrilla

subject

chemistry.chemical_compound Cerium chemistry Yield (chemistry)Polymer chemistry Supramolecular chemistry chemistry.chemical_element General Chemistry Buffer solution Self-assembly General Medicine Evaporation (deposition)Catalysis

description

Single crystals of Na40K6[Ni(H2O)6]3 [K@K7Ce24Ge12W120O456 (OH)12(H2O)64]· 178H2O are synthesized by addition of KCl to a NaOAc/AcOH buffer solution containing Ce(NO3)3, GeO2, Na2WO4, and NiCl2 followed by slow evaporation at room temperature (24% yield).

year	journal	country	edition	language
2010-09-22	Angewandte Chemie

https://doi.org/10.1002/ange.201004207

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