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RESEARCH PRODUCT
Capturing Hydrophobic Trifluoroiodomethane in Water into an M 4 L 6 Cage
Prasenjit MalKari RissanenChandan GiriChandan GiriPrasit Kumar Sahoosubject
Hydrophobic Trifluoroiodomethane010405 organic chemistrywaterSupramolecular chemistrychemistry010402 general chemistryPhotochemistry01 natural sciencesBinding constant0104 chemical sciencesCondensed Matter::Soft Condensed MatterInorganic ChemistryHydrophobic effectmetal–organic frameworkschemistry.chemical_compoundchemistryPhysics::Atomic and Molecular ClustersTrifluoroiodomethaneSelf-assemblyPhysics::Chemical PhysicsBenzeneCageHost–guest chemistryta116description
Synthetically important trifluoroiodomethane (CF3I) was trapped in water by using a metal–organic supramolecular anionic cage. Under ambient conditions, nearly 1:1 encapsulation of the hydrophobic, gaseous CF3I substrate with the cage was observed, and its binding constant was calculated by relative comparison with benzene encapsulation.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2016-10-10 | European Journal of Inorganic Chemistry |