Search results for "Trifluoroiodomethane"

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Capturing Hydrophobic Trifluoroiodomethane in Water into an M 4 L 6 Cage

2016

Synthetically important trifluoroiodomethane (CF3I) was trapped in water by using a metal–organic supramolecular anionic cage. Under ambient conditions, nearly 1:1 encapsulation of the hydrophobic, gaseous CF3I substrate with the cage was observed, and its binding constant was calculated by relative comparison with benzene encapsulation.

Hydrophobic Trifluoroiodomethane010405 organic chemistrywaterSupramolecular chemistrychemistry010402 general chemistryPhotochemistry01 natural sciencesBinding constant0104 chemical sciencesCondensed Matter::Soft Condensed MatterInorganic ChemistryHydrophobic effectmetal–organic frameworkschemistry.chemical_compoundchemistryPhysics::Atomic and Molecular ClustersTrifluoroiodomethaneSelf-assemblyPhysics::Chemical PhysicsBenzeneCageHost–guest chemistryta116European Journal of Inorganic Chemistry

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