6533b822fe1ef96bd127cce0

RESEARCH PRODUCT

A laboratory study of the mineralization and binding of 14C-labeled herbicide rimsulfuron in a rendzina soil

J.c. VédyT. ChoneL.o.y. MetzgerM.-j. BelgyFrancis AndreuxL.o.y. Munier-lamy

subject

Environmental EngineeringSOL POLLUEHealth Toxicology and Mutagenesis[SDE.MCG]Environmental Sciences/Global ChangesSoil respirationRendzinaSoilEnvironmental ChemistrySoil PollutantsUreaCarbon RadioisotopesIncubationSoil MicrobiologyTotal organic carbonMineralsChemistryHerbicidesPublic Health Environmental and Occupational HealthEnvironmental engineeringGeneral MedicineGeneral ChemistryMineralization (soil science)BiodegradationPollutionSoil contamination[SDE.MCG] Environmental Sciences/Global ChangesEnvironmental chemistryMicrocosm

description

Abstract The fate of pyrimidine-2- 14 C-rimsulfuron in a rendzina soil was investigated using a laboratory microcosm approach. Measurement of CO 2 evolution suggested that rimsulfuron applied at 5 times the recommended dose did not affect soil respiration. Under abiotic conditions, no mineralization of 14 C-rimsulfuron into 14 C-CO 2 occured and under biotic ones it was very low reaching 0.75 % of the applied 14 C-rimsulfuron after 246 days of incubation. The analysis of data showed that a three-half order model provided the best fit for the mineralization curve. Extractable 14 C-residues decreased over time to 70 – 80% of the applied 14 C-rimsulfuron at the end of the incubation. After 246 days of incubation, non extractable residues (NER) accounted for up to 24.7 % of the applied 14 C-rimsulfuron and were distributed according to organic carbon in soil size fractions, suggesting a progressive incorporation process of NER to soil humus.

https://hal.inrae.fr/hal-02688828