Acetylenes Rearranging on Ruthenium-Porphyrinogen and Leading to Vinylidene and Carbene Functionalities.

6533b822fe1ef96bd127d780

RESEARCH PRODUCT

Acetylenes Rearranging on Ruthenium-Porphyrinogen and Leading to Vinylidene and Carbene Functionalities.

Carlo Floriani Euro Solari Rosario Scopelliti Christine Stern Lucia Bonomo

subject

Transition metal carbene complex Acetylide chemistry.chemical_element Cumulene General Chemistry General Medicine Photochemistry Combinatorial chemistry Catalysis Ruthenium chemistry.chemical_compound chemistry Porphyrinogens Carbene

description

Through a proton-transfer reaction a porphyrinogen assists the transformation of terminal acetylenes into Ru-vinylidenes, which are the entry point to a variety of Ru-carbenes and Ru-cumulenes. The scheme (in which the porphyrinogen is stylized) shows the reversible interconversion of an acetylide into a divinylidene unit.

year	journal	country	edition	language
2001-04-17	Angewandte Chemie (International ed. in English)

https://pubmed.ncbi.nlm.nih.gov/29712350

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