Search results for "Porphyrinogens"

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Acetylenes Rearranging on Ruthenium-Porphyrinogen and Leading to Vinylidene and Carbene Functionalities.

2001

Through a proton-transfer reaction a porphyrinogen assists the transformation of terminal acetylenes into Ru-vinylidenes, which are the entry point to a variety of Ru-carbenes and Ru-cumulenes. The scheme (in which the porphyrinogen is stylized) shows the reversible interconversion of an acetylide into a divinylidene unit.

Transition metal carbene complexAcetylidechemistry.chemical_elementCumuleneGeneral ChemistryGeneral MedicinePhotochemistryCombinatorial chemistryCatalysisRutheniumchemistry.chemical_compoundchemistryPorphyrinogensCarbeneAngewandte Chemie (International ed. in English)

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