6533b822fe1ef96bd127d7e9

RESEARCH PRODUCT

Halogen bond directionality translates tecton geometry into self-assembled architecture geometry

Tullio PilatiMarco SacconeGiancarlo TerraneoGiancarlo TerraneoPierangelo MetrangoloPierangelo MetrangoloGiuseppe ResnatiGiuseppe ResnatiGabriella CavalloGabriella CavalloIvana PibiriAndrea Pace

subject

Halogen bondhalogen bond self-assemblyBent molecular geometryOxadiazoleGeometryGeneral ChemistrySettore CHIM/06 - Chimica OrganicaCondensed Matter PhysicsSelf assembledchemistry.chemical_compoundchemistryHalogenDirectionalityGeneral Materials Science

description

The structures of halogen-bonded infinite chains involving two diiodoperfluoroalkanes and a bent bis(pyrid-4′-yl)oxadiazole show that the geometry of the pyridyl pendant rings is translated into the angle between the formed halogen bonds.

10.1039/c3ce40268ahttp://hdl.handle.net/10447/74655