6533b823fe1ef96bd127e939
RESEARCH PRODUCT
Size-dependent photoemission shifts in small metal clusters
P. HuttunenRisto M. Nieminensubject
Physics and Astronomy (miscellaneous)ChemistryBinding energyInverse photoemission spectroscopySize dependentMetals and AlloysGeneral EngineeringAngle-resolved photoemission spectroscopyMetalCondensed Matter::Materials ScienceVacancy defectvisual_artPhysics::Atomic and Molecular Clustersvisual_art.visual_art_mediumCondensed Matter::Strongly Correlated ElectronsSPHERESAtomic physicsMetal clustersdescription
Density-functional calculations of the change in self-consistent-field energy ( Delta SCF) type are reported for core-level photoemission shifts in small metal spheres. The results for the atom-in-jellium vacancy model show that the binding energies are increased from bulk-metal values, but the photoemission shifts show considerable oscillations as a function of cluster size.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1986-05-01 | Journal of Physics F: Metal Physics |