0000000000527883

AUTHOR

P. Huttunen

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Size-dependent photoemission shifts in small metal clusters

1986

Density-functional calculations of the change in self-consistent-field energy ( Delta SCF) type are reported for core-level photoemission shifts in small metal spheres. The results for the atom-in-jellium vacancy model show that the binding energies are increased from bulk-metal values, but the photoemission shifts show considerable oscillations as a function of cluster size.

Physics and Astronomy (miscellaneous)ChemistryBinding energyInverse photoemission spectroscopySize dependentMetals and AlloysGeneral EngineeringAngle-resolved photoemission spectroscopyMetalCondensed Matter::Materials ScienceVacancy defectvisual_artPhysics::Atomic and Molecular Clustersvisual_art.visual_art_mediumCondensed Matter::Strongly Correlated ElectronsSPHERESAtomic physicsMetal clustersJournal of Physics F: Metal Physics
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