6533b823fe1ef96bd127f546
RESEARCH PRODUCT
Solid state anion–π interactions involving polyhalides
Markus AlbrechtTatjana RepenkoArto ValkonenKari RissanenChristian BohnenMichael Giesesubject
AnionsModels MolecularSpectrometry Mass Electrospray Ionizationmedicine.diagnostic_testChemistryElectrospray ionizationInorganic chemistryChemieSolid-stateAnalytical chemistryMass spectrometrymedicine.disease_causeMass spectrometricIonInorganic ChemistryHalogensSpectrophotometrymedicineSpectrophotometry Ultravioletta116Ultravioletdescription
The stabilization of polyhalides in the solid state with the support of electron-deficient pentafluorophenyl groups is described. Furthermore, a synthetic approach towards the sensitive tetraiodide dianion is described and ESI mass spectrometric evidence for its presence in solution is reported.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2013-11-22 | Dalton Trans. |