6533b823fe1ef96bd127f5c5

RESEARCH PRODUCT

Nanostructured anode material for Li-ion batteries

Catia ArbizzaniSalvatore PiazzaRosalinda InguantaMarina MastragostinoGermano FerraraCarmelo SunseriLibero Damen

subject

Materials scienceMetallurgyNanowireSNCO ALLOYElectrolyteElectrochemistrySnCo alloy template electrosynthesis alumina membrane anode lithium ion batteries electrochemical characterizationLithium-ion batteryAnodeSettore ING-IND/23 - Chimica Fisica ApplicataChemical engineeringALUMINA MEMBRANEElectrodeLITHIUM ION BATTERIESGraphiteANODETEMPLATE ELECTROSYNTHESISTemplate method pattern

description

The present paper focuses on a nanostructured SnCo alloy electrochemically prepared by template method in view of its use as anode material alternative to graphite in lithium-ion batteries. The fabrication of SnCo nanowire arrays was carried out by potentiostatic co-deposition of the two metals by using nanostructured anodic alumina membranes as template. Electrochemical tests on lithiation-delithiation of these SnCo electrodes in conventional organic electrolyte (EC:DMC LiPF6) at 30°C showed that their specific capacity was stable for about the first 12 cycles at a value near to the theoretical one for Li22Sn5 and, hence, progressively decayed.

http://hdl.handle.net/11585/91556