6533b824fe1ef96bd1280816
RESEARCH PRODUCT
Self‐Assembly and Characterisation of Grid‐Type Iron( II ), Cobalt( II ) and Zinc( II ) Complexes
Violetta PatroniakKari RissanenJean-marie LehnMaciej KubickiPaul N. W. BaxterMaija Nissinensubject
010405 organic chemistryLigandSupramolecular chemistrychemistry.chemical_elementZinc010402 general chemistry01 natural sciences0104 chemical sciencesIonInorganic ChemistryMetalCrystallographychemistryOctahedronvisual_artvisual_art.visual_art_mediumSelf-assemblyCobaltdescription
The reaction of the ligands 5 and 6, containing two tridentate binding units, with iron(II), cobalt(II) and zinc(II) leads to the self-assembly of supramolecular architectures of [2 × 2] grid type containing four ions in octahedral coordination sites. The grid-type structures have been assigned on the basis of the spectroscopic data in solution, and confirmed in the solid state in the case of complexes 6b and 6c by X-ray crystallography. The latter study revealed that each metal ion is situated in a distorted octahedral coordination environment comprising two N,N,O ligand donor sets. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2003-11-01 | European Journal of Inorganic Chemistry |