6533b824fe1ef96bd1280982

RESEARCH PRODUCT

Donor-π-Acceptor Species Derived from Functionalised 1,3-Dithiol-2-ylidene Anthracene Donor Units Exhibiting Photoinduced Electron Transfer Properties: Spectroscopic, Electrochemical, X-Ray Crystallographic and Theoretical Studies

Luis SánchezAndrew GreenIgor K. LednevEnrique OrtíRonald E. HesterAndrei S. BatsanovAdrian J. MooreMaría SavirónPedro M. ViruelaJohn N. MooreMartin R. BryceNazario MartínRafael ViruelaJudith A. K. HowardT. Q. YeMalcolm A. Coffin

subject

Steric effectsOrganic ChemistryDithiolGeneral ChemistryCrystal structurePhotochemistryAcceptorCatalysisPhotoinduced electron transferchemistry.chemical_compoundCrystallographyElectron transferchemistryAb initio quantum chemistry methodsIntramolecular force

description

Steric interactions between the anthraquinoid core and the 1,3-dithiole and dicyanomethylene groups play a key role in determining the physical properties of system 1. The intramolecular charge transfer properties of this donor–π-acceptor species have been explored and cyclic voltammetric data, X-ray crystal structures and ab initio calculations are also reported.

yearjournalcountryeditionlanguage
1998-12-04Chemistry - A European Journal
https://doi.org/10.1002/(sici)1521-3765(19981204)4:12<2580::aid-chem2580>3.0.co;2-8