6533b824fe1ef96bd1280afe

RESEARCH PRODUCT

Cooperative Thermal and Optical Switching of Spin States in a New Two-Dimensional Coordination Polymer

Ana B. GasparVirginie NielAna GaletAna GaletJosé Antonio RealM. Carmen Muñoz

subject

Switching ; Thermal ; Optical ; Low temperatures ; Hysteresis ; SpinSpin statesCoordination polymerUNESCO::QUÍMICAMolecular physics:QUÍMICA [UNESCO]CatalysisIonchemistry.chemical_compoundSpinSpin crossoverThermalMaterials ChemistryLow temperaturesSpin (physics)CouplingChemistryHysteresisRelaxation (NMR)Metals and Alloys:QUÍMICA::Química física [UNESCO]CROSSOVERGeneral ChemistrySurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsHysteresisCONVERSIONFISICA APLICADASwitchingUNESCO::QUÍMICA::Química físicaCeramics and CompositesOptical

description

{Fe(pmd)2[Cu(CN)2]2} (pmd = pyrimidine) displays a rigid two-dimensional structure and undergoes thermal- and optical-driven spin crossover behaviour; cooperative elastic coupling between iron(II) ions in the framework induces thermal hysteresis in the HS↔LS conversion and sigmoidal HS→LS relaxation of the photo-induced HS state at low temperatures. Niel, Virginie, Virginie.Niel@uv.es ; Galet Domingo, Ana Guadalupe, Ana.Galet@uv.es ; Gaspar Pedros, Ana Belen, Ana.B.Gaspar@uv.es ; Real Cabezos, Jose Antonio, Jose.A.Real@uv.es

yearjournalcountryeditionlanguage
2003-06-18
10.1039/b301806ghttps://dx.doi.org/10.1039/B301806g