6533b825fe1ef96bd1281d13

RESEARCH PRODUCT

Hydrated Layer Formation on Tricalcium and Dicalcium Silicate Surfaces: Experimental Study and Numerical Simulations

André NonatSandrine Garrault And

subject

Degree of reactionMaterials scienceNucleationMineralogySurfaces and Interfacesengineering.materialCondensed Matter PhysicsSilicatechemistry.chemical_compoundParticle aggregationchemistryChemical engineeringElectrochemistryAnhydrousengineeringGeneral Materials ScienceCalcium silicate hydrateLayer (electronics)SpectroscopyLime

description

In this paper, an original approach is used to study the calcium silicate hydrate (C−S−H) layer formation on the surface of grains of anhydrous silicate during tricalcium and dicalcium silicate hydration from the variation of the rate of hydration with lime concentration. The effects of C−S−H nucleation and growth on the curves for the degree of reaction against time have been separated in both experimental study of the rate of hydration in controlled conditions and numerical simulation of the growth of C−S−H on a surface from a particle aggregation model. The influence of the number of nuclei and of the different growth modes has been quantified.

https://doi.org/10.1021/la011201z