6533b825fe1ef96bd12820c2
RESEARCH PRODUCT
Synthesis and crystal structure of an unprecedented bismuth porphyrin containing ester pendant arms
Philippe RichardLydie MichaudetBernard Boitrelsubject
StereochemistryDimerchemistry.chemical_elementCrystal structure010402 general chemistry01 natural sciences[ CHIM ] Chemical SciencesCatalysisBismuthIonchemistry.chemical_compoundMaterials Chemistry[CHIM]Chemical SciencesCoordination geometrySquare antiprismatic molecular geometry010405 organic chemistryChemistryMetals and AlloysGeneral ChemistryPorphyrin0104 chemical sciences3. Good healthSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCrystallographyCeramics and Compositesdescription
International audience; An easily prepared porphyrin with pendant arms is shown to form a stable complex with bismuth(III) ion; the complex is eight coordinate with a square antiprismatic coordination geometry; the solid-state structure exhibits the formation of a dimer assembled via mutual coordination of a terminal ester group.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2000-01-01 |