6533b825fe1ef96bd12826ce
RESEARCH PRODUCT
COMMUNICATION. OBSERVATIONS ON THE 121-Sb MÖSSBAUER PARAMETERS OF ANTIMONY (III) COMPOUNDS FEATURING A PYRAMIDAL SbS3SKELETAL UNIT
F. MaggioGiuseppe AlonzoN. BertazziM. Consigliosubject
Coupling constantChemistryOrganic ChemistryInorganic chemistrychemistry.chemical_elementBiochemistrySecondary bondsInorganic ChemistryCrystallographyAntimonyMössbauer spectroscopyQuadrupoleLinear correlationLone pairUnit (ring theory)description
Abstract A linear correlation between the chemical isomer shift and the quadrupole coupling constant for a number of antimony tris-thiolates has been evidenced. This behaviour can be rationalized on considering a modulation of the s/p character of the lone pair of electrons from the influence of secondary bonds.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1991-02-01 | Phosphorus, Sulfur, and Silicon and the Related Elements |