6533b825fe1ef96bd1283095
RESEARCH PRODUCT
Synthesis ofo-thiatelluraphenylenezirconocenes. X-ray crystal structure of
Bernard GautheronMarek M. KubickiH. LavayssierePascale TavaresPhilippe MeunierG. DousseJ. Satgesubject
ChemistryStereochemistryBent molecular geometryMetals and AlloysCrystal structureMetallacycleInorganic ChemistryCrystallographychemistry.chemical_compoundYield (chemistry)X-ray crystallographyMaterials ChemistryMoleculeMetalloceneOrganometallic chemistrydescription
o-Thiatelluraphenylenezirconocene complexes were obtained in good yield by reaction of dilithiumo-benzenthiatelluride with zirconocene dichlorides. These compounds represent the first examples of heterodichalcogenaphenylene bent metallocences. They were characterized by spectroscopic methods and the effect on the n.m.r. results of stepwise substitution of one and two Te atoms for S is discussed.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1992-06-01 | Transition Metal Chemistry |