Micelles Formed by Cylindrical Brush-Coil Block Copolymers

6533b825fe1ef96bd1283158

RESEARCH PRODUCT

Micelles Formed by Cylindrical Brush-Coil Block Copolymers

Manfred Schmidt Nikhil Gunari Karl Fischer Nikos Hadjichristidis Giorgos Gkogkas Nawel S. Khelfallah

subject

chemistry.chemical_classification Materials science Polymers and Plastics Organic Chemistry Polymer Micelle chemistry.chemical_compound chemistry Block (telecommunications)Polymer chemistry Amphiphile Materials Chemistry Copolymer Side chain Polystyrene Acrylic acid

description

Amphiphilic cylindrical brush-coil block copolymers consisting of a polystyrene coil and a cylindrical brush block with poly(acrylic acid) side chains are prepared by ATRP of t-butylacrylate from a block comacroinitiator. Upon acidolysis of the poly(t-butylacrylate), water-soluble polymers were obtained that were observed to form micelles consisting of 4-5 block copolymers on average in aqueous solution. The star-like nature of such micelles was clearly visualized by scanning force microscopy.

year	journal	country	edition	language
2005-11-01	Macromolecular Rapid Communications

https://doi.org/10.1002/marc.200500512

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