6533b825fe1ef96bd1283185
RESEARCH PRODUCT
Zinn - Chalkogen - Heterocyclen. I. 2.4.6-Hexamethyl-1.3.5-triselena-2.4.6-tristannacyclohexan, Massen- und Schwingungsspektren
B. MathiaschA. Blechersubject
CrystallographyFragmentation (mass spectrometry)chemistryStereochemistryCyclohexane conformationMass spectrumMoleculechemistry.chemical_elementGeneral ChemistryVibration spectraSulfurdescription
The mass spectrum of the title compound exhibits very similar fragmentation patterns compared with the sulfur analogon. The high stability of triply coordinated organotin cations is remarkable. There is no evidence for any stabilisation effects by pπ-dπ bonding concerning the ring bonds. The assignment of the vibration spectra leads to the conclusion that the molecule of triselenastanninane possesses a boat conformation.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2010-09-01 | Bulletin des Sociétés Chimiques Belges |