6533b826fe1ef96bd1283a82
RESEARCH PRODUCT
The structure and dynamics of Cl-substituted tetraphenyl- and tetrabenzyl-tin(IV)
Markus SchürmannRenato BarbieriMaria Assunta GirasoloArturo SilvestriGiuseppe RuisiAdriana Barbieri PaulsenFriedo Hubersubject
Organic Chemistrychemistry.chemical_elementCrystal structureBiochemistryInorganic ChemistryCrystalMolecular dynamicsCrystallographychemistryMössbauer spectroscopyMaterials ChemistryMoleculePhysical and Theoretical ChemistryTindescription
Abstract The crystal and molecular structure of (o-ClC6H4CH2)4Sn has been determined by X-ray crystallography. Tin is in a slightly distorted environment. The molecular dynamics of (p-ClC6H4)4Sn, (o-ClC6H4)4Sn and (o-ClC6H4CH2)4Sn have been investigated by variable temperature 119Sn Mossbauer spectroscopy (VTMS). A Debye-solid behaviour has been detected for (p-ClC6H4)4Sn, where, on the other hand, no influence by hydrogen–chlorine interaction on the magnitude of the dynamics data and functions seems to occur. For the o-Cl-substituted derivatives, a non-Debye-solid character could be advanced.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1999-07-01 | Journal of Organometallic Chemistry |