ChemInform Abstract: Catalytic Enantioselective Addition of Terminal Alkynes to Aromatic Aldehydes Using Zinc-Hydroxyamide Complexes.

6533b826fe1ef96bd1283ac7

RESEARCH PRODUCT

ChemInform Abstract: Catalytic Enantioselective Addition of Terminal Alkynes to Aromatic Aldehydes Using Zinc-Hydroxyamide Complexes.

Gonzalo Blay Luz Cardona M. Carmen Muñoz Alicia Marco‐aleixandre José R. Pedro Isabel Fernández

subject

chemistry.chemical_classification Ligand Aryl Enantioselective synthesis chemistry.chemical_element General Medicine Zinc Combinatorial chemistry Catalysis chemistry.chemical_compound chemistry Reagent Organocatalysis Alkyl

description

A mandelamide ligand, derived from (S)-mandelic acid and (S)-phenylethanamine, catalyzes the addition of aryl-, alkyl- and silyl-alkynylzinc reagents to aromatic and heteroaromatic aldehydes with good yields and good to high enantioselectivities.

year	journal	country	edition	language
2010-02-23	ChemInform

https://doi.org/10.1002/chin.201008027

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