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RESEARCH PRODUCT

“Cp*Ir(III)” Complexes with Hemicleaveable Ligands of the Type N-Alkenyl Imidazolin-2-ylidene. Reactivity and Catalytic Properties

Rosa CorberanAnd Mercedes SanaúEduardo Peris

subject

Inorganic ChemistryTransmetalationChemistryOrganic ChemistryReactivity (chemistry)Physical and Theoretical ChemistryMedicinal chemistryCatalysis

description

A series of Cp*Ir(III) complexes with N-alkenyl imidazole-2-ylidene ligands have been obtained by transmetalation of the previously obtained silver−carbene species. Two structural and electronic pa...

https://doi.org/10.1021/om070188w