6533b826fe1ef96bd1284031
RESEARCH PRODUCT
Selective gas adsorption by calixarene-based porous octahedral M32 coordination cages
Ivan KhariushinAlexander OvsyannikovStéphane BaudronJas WardAnniina KiesiläKari RissanenElina KaleniusKonstantin KovalenkoVladimir FedinSvetlana SolovievaIgor AntipinVéronique BulachSylvie Ferlaysubject
huokoisuuskaasutkarboksyylihapotsupramolekulaarinen kemiakompleksiyhdisteetkobolttiadsorptiodescription
Giant octahedral M32 coordination cages were prepared via self-assembly of sulfonylcalix[4]arene-supported tetranuclear M(II) clusters (M = Co, Ni) with hybrid linker based on tris(dipyrrinato)cobalt(III) complexes appended with peripherical carboxylic groups. Due to intrinsic and extrinsic porosity, the obtained solid-state supramolecular architectures demonstrated good performance as adsorbents for the separation of industrially important gases mixtures. peerReviewed
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2022-01-01 |