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RESEARCH PRODUCT

Quartz Crystal Microbalance And Electrical Impedance Characterization Of Nickel Dissolution Process.

Francisco VicenteJ. GregoriJosé Juan García-jareñoDavid Giménez-romero

subject

NickelMaterials scienceReaction rate constantchemistryPassivationDesorptionInorganic chemistryAnalytical chemistrychemistry.chemical_elementQuartz crystal microbalanceDissolutionDeposition (law)Anode

description

Abstract. The anodic nickel dissolution in acid media is analysed by means of EQCM and EIS techniques. The experimental impedance spectra have been fitted to the equivalent circuit which corresponds to two consecutive electron transfers followed by a Ni(II) desorption. That way rate constants and surface concentrations of the Ni(0) and Ni(I) species are obtained. EQCM also provides information about the mechanism of deposition and passivation of nickel as well as the hydrogen evolution.

yearjournalcountryeditionlanguage
2005-01-01
https://doi.org/10.1016/b978-008044648-6.50083-5