6533b826fe1ef96bd128464e

RESEARCH PRODUCT

Iodine oxidative coupling of diene and triene-diolates of unsaturated carboxylic acids.

Salvador GilMargarita ParraRamon MestresMaría José AurellA. Tortajada

subject

chemistry.chemical_compoundDieneChemistryOrganic ChemistryDrug DiscoveryOrganic chemistrychemistry.chemical_elementOxidative coupling of methaneIodineBiochemistry

description

Abstract Oxidative Coupling of the dianions of unsaturated carboxylic acids 1 , and 4 with iodine, which provides a convenient and facile preparation of γ,γ and e,e-dicarboxylic acids 2 and 5, apparently occurs through SET substitution of intermediate iodo-carboxylates.

https://doi.org/10.1016/s0040-4020(01)96111-3