6533b826fe1ef96bd12848f1
RESEARCH PRODUCT
Polymorphism in Cs[AgZn(NCS)4].
Minna GuenesJussi Valkonensubject
StereochemistrySpace groupchemistry.chemical_elementGeneral MedicineCrystal structureZincMolecular biologyGeneral Biochemistry Genetics and Molecular BiologyIonCrystallographyDelocalized electronchemistryPolymorphism (materials science)CaesiumMoleculedescription
The title compound, caesium silver zinc tetrathiocyanate, crystallizes in two polymorphic forms, in space groups P2(1)/n and C2/c. Both structures form a continuous three-dimensional network. The structure in C2/c contains a delocalized Ag atom in a binuclear-like anion, where two [Ag(NCS)(4)] units (delocalized Ag as an average) share two common NCS(-) ligands.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2002-11-08 | Acta crystallographica. Section C, Crystal structure communications |