6533b826fe1ef96bd1285054

RESEARCH PRODUCT

[TiPHOS(Rh)]+:  A Fortuitous Coordination Mode and an Effective Hydrosilylation Bimetallic Catalyst

Pierre Le GendrePhilippe RichardClaude MoïseVirginie Comte

subject

Inorganic Chemistrychemistry.chemical_compoundchemistryHydrosilylationOrganic ChemistryPolymer chemistryOrganic chemistryPhysical and Theoretical ChemistryBimetallic stripCatalysis

description

The reaction of the titanocene diphosphine {(η5-C5H5)[η5-C5Me3-1,2-(PPh2)2]TiCl2} (TiPHOS; 1) with [Rh(COD)2](OTf) led to the new early−late heterobimetallic complex [(TiPHOS)Rh(COD)](OTf) (2), who...

yearjournalcountryeditionlanguage
2005-02-25Organometallics
https://doi.org/10.1021/om040058c