6533b826fe1ef96bd1285129

RESEARCH PRODUCT

Supramolecular Nanocycles Comprisingβ-Cyclodextrin-click-Ferrocene Units: Rings of Rings of Rings

Ute KolbHelmut RitterMaricica Munteanu

subject

chemistry.chemical_classificationPolymers and PlasticsCyclodextrinOrganic ChemistrySupramolecular chemistrymacromolecular substancesCycloadditionInclusion compoundchemistry.chemical_compoundchemistryFerrocenePolymer chemistry13-Dipolar cycloadditionMaterials ChemistryProton NMROrganic chemistryMetallocene

description

We applied 1,3-dipolar cycloaddition to bind ethynylferrocene onto 6I-azido-6I-deoxycyclomaltoheptaose under microwave assisted conditions. The process was investigated by (1) H NMR, FT-IR spectroscopy, and MALDI-TOF mass spectrometry. The ability of the synthesized compound to self-organize to cyclic supramolecular structures was investigated by dynamic light scattering measurements and cryo-transmission electron microscopy.

https://doi.org/10.1002/marc.200900754