6533b826fe1ef96bd1285129
RESEARCH PRODUCT
Supramolecular Nanocycles Comprisingβ-Cyclodextrin-click-Ferrocene Units: Rings of Rings of Rings
Ute KolbHelmut RitterMaricica Munteanusubject
chemistry.chemical_classificationPolymers and PlasticsCyclodextrinOrganic ChemistrySupramolecular chemistrymacromolecular substancesCycloadditionInclusion compoundchemistry.chemical_compoundchemistryFerrocenePolymer chemistry13-Dipolar cycloadditionMaterials ChemistryProton NMROrganic chemistryMetallocenedescription
We applied 1,3-dipolar cycloaddition to bind ethynylferrocene onto 6I-azido-6I-deoxycyclomaltoheptaose under microwave assisted conditions. The process was investigated by (1) H NMR, FT-IR spectroscopy, and MALDI-TOF mass spectrometry. The ability of the synthesized compound to self-organize to cyclic supramolecular structures was investigated by dynamic light scattering measurements and cryo-transmission electron microscopy.
year | journal | country | edition | language |
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2010-04-06 | Macromolecular Rapid Communications |