6533b827fe1ef96bd1285f0d
RESEARCH PRODUCT
Extending the Series: Synthesis and Characterization of a Dicationic N-Heterocyclic Selenium Carbene Analogue
Jason DuttonHeikki TuononenMichael JenningsPaul Ragognasubject
seleenidikationiN-heterosykliset karbeenitN-heterocyclic carbenesselenium dicationdescription
The room-temperature reaction between the Dipp2DAB ligand, SnCl2, and SeCl4 results in the quantitative formation of a dicationic N-heterocyclic “carbenoid”. This represents the first example of a chalcogenium dication that mimics the ubiquitous Arduengo-type carbenes; however, the electronic structure is significantly different. peerReviewed
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2006-01-01 |