Search results for "seleenidikationi"

Extending the Series: Synthesis and Characterization of a Dicationic N-Heterocyclic Selenium Carbene Analogue

2006

The room-temperature reaction between the Dipp2DAB ligand, SnCl2, and SeCl4 results in the quantitative formation of a dicationic N-heterocyclic “carbenoid”. This represents the first example of a chalcogenium dication that mimics the ubiquitous Arduengo-type carbenes; however, the electronic structure is significantly different. peerReviewed