Phosphororganische Verbindungen, XVIII Phosphinimino-Verbindungen aus Phosphindihalogeniden und primären Aminen

6533b827fe1ef96bd12863b7

RESEARCH PRODUCT

Phosphororganische Verbindungen, XVIII Phosphinimino-Verbindungen aus Phosphindihalogeniden und primären Aminen

subject

Chemistry Organic Chemistry Physical and Theoretical Chemistry Medicinal chemistry

description

Triphenylphosphindihalogenide setzen sich mit primaren aromatischen Aminen zu Triphenylphosphiniminen um; mit entsprechenden aromatischen Diaminen werden Bis-phosphinimine erhalten. Mit Ammoniak, primaren aliphatischen Aminen, Hydrazin und Phenylhydrazin bilden sich Amidophosphoniumsalze, mit Schwefelwasserstoff erhalt man Triphenylphosphinsulfid. — Die UV- und IR-Spektren der dargestellten Phosphinimine und einiger Phosphin- bzw. Arsinmethylen werden mitgeteilt.

year	journal	country	edition	language
1959-11-27	Justus Liebigs Annalen der Chemie

https://doi.org/10.1002/jlac.19596270115

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